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Holistic Cell Design by Berkeley Lab Scientists Leads to High-Performance, Long Cycle-Life Lithium-Sulfur Battery

Battery could find use in mobile applications, and eventually, electric vehicles with 300-mile range

November 19, 2013
Allan Chen 510-486-4210  a_chen@lbl.gov
News Release

Researchers at the U.S. Department of Energy’s Lawrence Berkeley National Laboratory  (Berkeley Lab) have demonstrated in the laboratory a lithium-sulfur (Li/S) battery that has more than twice the specific energy of lithium-ion batteries, and that lasts for more than 1,500 cycles of charge-discharge with minimal decay of the battery’s capacity. This is the longest cycle life reported so far for any lithium-sulfur battery.

A schematic of a lithium-sulfur battery with SEM photo of silicon-graphene oxide material.

A schematic of a lithium-sulfur battery with SEM photo of sulfur-graphene oxide material.

Demand for high-performance batteries for electric and hybrid electric vehicles capable of matching the range and power of the combustion engine encourages scientists to develop new battery chemistries that could deliver more power and energy than lithium-ion batteries, currently the best performing battery chemistry in the marketplace.

For electric vehicles to have a 300-mile range, the battery should provide a cell-level specific energy of 350 to 400 Watt-hours/kilogram (Wh/kg). This would require almost double the specific energy (about 200 Wh/kg) of current lithium-ion batteries. The batteries would also need to have at least 1,000, and preferably 1,500 charge-discharge cycles without showing a noticeable power or energy storage capacity loss.

“Our cells may provide a substantial opportunity for the development of zero-emission vehicles with a driving range similar to that of gasoline vehicles,” says Elton Cairns, of the Environmental Energy Technologies Division (EETD) at Berkeley Lab.

Long-term cycling test results of the Li/S cell with CTAB-modified S-GO composite cathodes. This result represents the longest cycle life (exceeding 1500 cycles) with an extremely low decay rate (0.039% per cycle) demonstrated so far for a Li/S cell.

Long-term cycling test results of the Li/S cell with CTAB-modified S-GO composite cathodes. This result represents the longest cycle life (exceeding 1500 cycles) with an extremely low decay rate (0.039% per cycle) demonstrated so far for a Li/S cell.

The battery initially showed an estimated cell-specific energy of more than 500 Wh/kg and it maintained it at >300 Wh/kg after 1,000 cycles—much higher than that of currently available lithium-ion cells.

The team is now seeking support for the continuing development of the Li/S cell, including higher sulfur utilization, operation under extreme conditions, and scale-up. Partnerships with industry are being sought. The next steps in the development are to further increase the cell energy density, improve cell performance under extreme conditions, and scale up to larger cells.

The results were reported in the journal Nano Letters, in a paper authored by Min-Kyu Song (Molecular Foundry, Berkeley Lab), Yuegang Zhang (Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences) and Cairns (Environmental Energy Technologies Division, Berkeley Lab). The research was funded by the U.S. Department of Energy’s Office of Science and a University of California Proof of Concept Award.

For a more detailed discussion of the technology, see here.

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The Molecular Foundry is one of five DOE Nanoscale Science Research Centers (NSRCs), national user facilities for interdisciplinary research at the nanoscale, supported by the DOE Office of Science. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize, and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE’s Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos national laboratories.  For more information about the DOE NSRCs, please visit science.energy.gov/bes/suf/user-facilities/nanoscale-science-research-centers/.

DOE’s Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit science.energy.gov


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